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Science
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The different oxoanions of a given nonmetal atom will differ substantially in their basicities. For example, chlorine forms four different oxoanions: ClO-, ClO2-, ClO3-, ClO4-. ClO- has a pKb of 6.5; ClO2- 12.1 while the pKb value of the other two oxoanions are such weak bases that their hydrolysis in not measureable...
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Adding additional oxygens decreases the basicity of the oxoanion. Each additional oxo group increases the pKb value by about 5.7 units.
Effect of Electronegativity
As the electronegativity of the nonmetal atom decreases the basicity of the oxo anion increases. Comparing the pKb values orClO-, 6.50; BrO-, 5...
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