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Topic: Philosophy
Number of pages / Number of words: 3 / 582
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The alternative interpretation of the probability distribution (for a stationary state of an atom) as a representation of a static distribution of electronic charge in real space is stressed, in preparation for the discussion of the chemical bond.

Chemical binding is discussed in terms of the molecular charge distribution and the forces which it exerts on the nuclei, an approach which may be rigorously presented using electrostatic concepts...

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The discussion is enhanced through the extensive use of diagrams to illustrate both the molecular charge distributions and the changes in the atomic charge distributions accompanying the formation of a chemical bond.

The above topics are covered in the first seven sections of this web page. The final section is for the reader interested in the extension of the orbital concept to the molecular cases...

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