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Both gases undergo a few chemical reactions before they become the acids present in acid rain. The two main phases are the gas phase and the aqueous phase.
As far as sulpur dioxide is concerned there is a range of possible reactions that may lead to the oxidation of the gas in the atmosphere each having a different degree of success...
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One option is the photooxidation of the gas by ultraviolet light. This reaction has been found to be an unimportant supplier to the creation of sulphuric acid.
Another route that is more common is the one where sulphur dioxide is oxidized to form a sulphite ion.
SO2 (g) + o2 (g) a SO32-
After this the sulphite ion forms sulphuric acid when it comes into contact with the moisture in the atmosphere...
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